One-pedal driving on the Polestar 2 is definitely a cool feature but Regen braking is what slows you down most of the time in one-pedal mode, converting kinetic energy back into electricity. (Geek mode)
The mechanical brakes kick in when you need more stopping power, like in a hard stop or when regen isn't enough at very low speeds.
It can be tricky to tell exactly when the mechanical brakes are engaging, but a good clue is if you feel the car slowing down more sharply than usual, or if you hear a slight squeal or feel a subtle change in pedal feel. Basically, if you're stopping smoothly and gently, it's probably mostly regen, if you're braking harder, the mechanical brakes are likely helping out.